Why Does Stainless Steel Also Rust

Aug 01, 2022

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When brown rust spots (spots) appear on the surface of stainless steel pipes, people are amazed: "Stainless steel does not rust, and if it rusts, it is not stainless steel, and there may be a problem with the steel." In fact, this is a one-sided misconception about the lack of understanding of stainless steel. Stainless steel will also rust under certain conditions. 

Stainless steel has the ability to resist atmospheric oxidation—that is, rust resistance, and also has the ability to resist corrosion in media containing acids, alkalis, and salts—that is, corrosion resistance. However, the size of its anti-corrosion ability varies with the chemical composition of its steel itself, the state of mutual addition, the conditions of use and the type of environmental media. For example, 304 steel pipe has absolutely excellent anti-corrosion ability in a dry and clean atmosphere, but if it is moved to the seaside area, it will rust soon in the sea fog containing a lot of salt; while the 316 steel pipe shows good. Therefore, it is not any kind of stainless steel that can resist corrosion and rust in any environment. 

Stainless steel is a very thin, firm, fine and stable chromium-rich oxide film (protective film) formed on its surface to prevent the continuous infiltration and oxidation of oxygen atoms, so as to obtain the ability to resist rust. Once for some reason, this film is constantly damaged, oxygen atoms in the air or liquid will continue to infiltrate or iron atoms in the metal will continue to separate out, forming loose iron oxide, and the metal surface will be continuously corroded.

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